Perkin Reaction
Perkins published a total synthesis of the putative structure in 2005 and observed discrepancies in the chemical shift values of 1H and 13C NMR suggesting a diastereomeric relationship of the originally assigned and synthesized structure and the actual natural product.
Perkins published a total synthesis of the putative structure in 2005 and observed discrepancies in the chemical shift values of 1H and 13C NMR suggesting a diastereomeric relationship of the originally assigned and synthesized structure and the actual natural product.